Search results for "chiral [model]"
showing 10 items of 83 documents
Odd parity bottom-flavored baryon resonances
2013
The LHCb Collaboration has recently observed two narrow baryon resonances with beauty. Their masses and decay modes look consistent with the quark model orbitally excited states Lambda(b)(5912) and Lambda(b)*(5920), with quantum numbers J(P) = 1/2(-) and 3/2(-), respectively. We predict the existence of these states within a unitarized meson-baryon coupled-channel dynamical model, which implements heavy-quark spin symmetry. Masses, quantum numbers and couplings of these resonances to the different meson-baryon channels are obtained. We find that the resonances Lambda(0)(b)(5912) and Lambda(0)(b)(5920) are heavy-quark spin symmetry partners, which naturally explains their approximate mass de…
Catalytic Enantioselective Aza-Reformatsky Reaction with Cyclic Imines
2016
A catalytic highly enantioselective aza-Reformatsky reaction with cyclic aldimines and ketimines for the synthesis of chiral b-amino esters with good yields and excellent enantioselectivities is reported.Areadily available diaryl prolinol is used as a chiral ligand, ZnMe2 as a zinc source and ethyl iodoacetate as reagent in the presence of air atmosphere. The reaction with cyclic ketimines generates a quaternary stereocenter with excellent levels of enantioselectivity. Furthermore, five-membered N-sulfonyl ketimines were used as electrophiles with good enantiomeric excesses, under the optimized reaction conditions. Moreover, several chemical transformations were performed with the chiral b-…
Exploring the D* rho system within QCD sum rules
2013
We present a study of the D* rho system made by using the method of QCD sum rules to determine the mass of possible resonances generated in the same system. Using isospin and spin projectors, we investigate the different configurations and obtain evidences for three D* mesons with isospin I = 1/2, spin S = 0, 1, 2 and with masses 2500 +/- 67, 2523 +/- 60, and 2439 +/- 119 MeV, respectively. The last state can be associated with D-2*(2460) ( spin 2) listed by the Particle Data Group, while one of the first two might be related to D* (2640), with unknown spin parity. In the case of I = 3/2 we also find evidences of three states with spin 0, 1, and 2, respectively, with masses 2467 +/- 82, 242…
Deeply bound levels in kaonic atoms
2000
Using a microscopic antikaon-nucleus optical potential recently developed by Ramos and Oset (nucl-th/9906016, in print in Nuclear Physics A) from a chiral model, we calculate strong interaction shifts and widths for $K^-$ atoms. This purely theoretical potential gives an acceptable description of the measured data ($\chi^2/{\rm num.data}= 3.8$), though it turns out to be less attractive than what can be inferred from the existing kaon atomic data. We also use a modified potential, obtained by adding to the latter theoretical one a s-wave term which is fitted to known experimental kaonic data ($\chi^2/{\rm degree of freedom}= 1.6$), to predict deeply bound $K^-$ atomic levels, not detected y…
Enantioselective zinc-mediated conjugate alkynylation of saccharin-derived 1-aza-butadienes
2020
The enantioselective 1,4-alkynylation of conjugated imines derived from saccharin with aryl- and alkyl-substituted terminal alkynes has been achieved. The reaction mediated by diethylzinc in the presence of a catalytic amount of a bis(hydroxy)malonamide chiral ligand provides the corresponding imines bearing a propargylic stereocenter with moderate yields and fair to excellent enantioselectivities.
Hirālu piridīna organokatalizatoru izstrāde un pielietojums
2015
Maģistra darba ietvaros tika izstrādāta hirālu DMAP organokatalizatoru sintēze. Iegūto organokatalizatoru aktivitāte tika pārbaudīta tetrazola hemiaminālu dinamiskajā kinētiskajā sadalīšanā.
tau -> pi pi pi nu(tau) decays and the a(1)(1260) off-shell width revisited
2009
The tau -> pi pi pi nu(tau) decay is driven by the hadronization of the axial-vector current. Within the resonance chiral theory, and considering the large-N-C expansion, this process has been studied in Ref. [1] (D. Gomez Dumm, A. Pich, J. Portoles, 2004). In the light of later developments we revise here this previous work by including a new off-shell width for the lightest a(1) resonance that provides a good description of the tau -> pi pi pi nu(tau) spectrum and branching ratio. We also consider the role of the rho(1450) resonance in these observables. Thus we bring in an overall description of the tau -> pi pi pi nu(tau) process in excellent agreement with our present experimental know…
Light flavor and heavy quark spin symmetry in heavy meson molecules
2012
We propose an effective field theory incorporating light SU(3)-flavor and heavy quark spin symmetry to describe charmed meson-antimeson bound states. At lowest order the effective field theory entails a remarkable simplification: it only involves contact range interactions among the heavy meson and antimeson fields. We show that the isospin violating decays of the X(3872) can be used to constrain the interaction between the D and a (D) over bar* mesons in the isovector channel. As a consequence, we can rule out the existence of an isovector partner of the X(3872). If we additionally assume that the X(3915) and Y(4140) are D*(D) over bar* and D*(s)(D) over bar*(s) molecular states, we can de…
Low-energy couplings of QCD from current correlators near the chiral limit
2004
We investigate a new numerical procedure to compute fermionic correlation functions at very small quark masses. Large statistical fluctuations, due to the presence of local ``bumps'' in the wave functions associated with the low-lying eigenmodes of the Dirac operator, are reduced by an exact low-mode averaging. To demonstrate the feasibility of the technique, we compute the two-point correlator of the left-handed vector current with Neuberger fermions in the quenched approximation, for lattices with a linear extent of L~1.5 fm, a lattice spacing a~0.09 fm, and quark masses down to the epsilon-regime. By matching the results with the corresponding (quenched) chiral perturbation theory expres…
Ligands P-stéréogéniques dérivés du calix[4]arène. Synthèses et applications en catalyse asymétrique
2010
We were interested in synthesis of P-stereogenic ligands derived from calix[4]arene and in their application in asymmetric catalysis. Mono et diphosphines were prepared on the upper rim of the macrocyle starting from the mono or dianion of the calix[4]arene and chlorophosphines borane or the oxazaphospholidine borane complex. The best selectivity was obtained by reaction of the dianion with the oxazaphospholidine borane complex leading to a bisaminophosphine borane. After acidolysis with HCl giving the corresponding bischlorophosphine and reaction with organolithium reagents, diphosphines diborane were obtained with good yields (40 à 60 %). X-ray structures of the prepared ligands confirmed…